April 26, 2023   |   Reading time: 5 minutes

CLP Hazard Warning Symbol: Gas Cylinder Pictogram 

CLP Hazard Warning Symbol: Gas Cylinder Pictogram
In this blog, we will delve into the significance of the gas cylinder pictogram and explore the safety measures that should be taken when dealing with products that bear this emblem. Also, we will discuss the potential risks associated with gas cylinders and provide practical tips on how to store products featuring the gas cylinder pictogram to minimise accidents and ensure a safe environment for both users and bystanders.

Whether you already handle products with gas cylinders or are simply interested in learning more about the necessary safety precautions, this blog post will provide you with valuable insights to protect yourself and others from potential hazards.

What does the gas cylinder pictogram mean?

Gas under pressure pictogram
This CLP pictogram signifies the presence of a gas under pressure within the container, or which are liquified or liquified and refrigerated. The hazards presented by these products are related to the high pressure or cold temperatures.

What are gases under pressure?

Here are the nuances of substances stored under pressure. Gases under pressure, for instance, are those confined within containers at a pressure of 200 kPa (kilopascal) or higher at 20°C. They are grouped based on their physical state when packaged:

  1. Compressed gases: Notable examples include oxygen and helium. These gases remain in a gaseous state within their containers due to high pressure.
  2. Liquefied gases: Think of butane and carbon dioxide. They transition into a liquid state under pressure, allowing for storage at room temperature.
  3. Refrigerated liquefied gases (Cryogenic gases): Liquid nitrogen belongs here. These demand extreme cold to stay in a liquid form and require specialised handling.
  4. Dissolved gases: Acetylene is a prime example, existing in a liquid solvent. Handling differs from traditional gases.

Moreover, chemicals under pressure constitute another category, comprising liquid or solid substances (like pastes or powders) with a gas pressurized at 200 kPa (kilopascal) or more at 20°C. These chemicals are further categorised based on flammable compound content and heat of combustion.

Understanding these classifications is fundamental for safe storage and handling in various industries, ensuring compliance with stringent safety protocols.

Hazard classes represented by the gas cylinder pictogram

The two Hazard Classes represented are ‘Gases under pressure’ and ‘Chemicals under pressure’. Take a look at each of these hazard classes in relation to signal words, hazard statements and hazard codes below.

Gases under pressure

Hazard class represented by the gas cylinder pictogram - Gases under pressure

Chemicals under pressure

Hazard class represented by the gas cylinder pictogram - Chemicals under pressure

The implications of gases under pressure

This symbol serves as an immediate warning that the contents are under significant pressure, and if mishandled or exposed to heat, they could potentially explode, resulting in severe burns or injuries. The risk intensifies when the gas is of the refrigerated variety, as it can lead to cryogenic burns or injuries, a hazard that should not be taken lightly.

In a workplace setting, gases under pressure wield the potential for swift and substantial gas discharge, carrying the inherent risk of health and fire-related dangers, contingent upon the gas’s properties. Such discharge may occur either by a deliberate act of opening the cylinder valve or, more critically, through an inadvertent release stemming from a damaged or leaking valve.

Of concern is the prospect of damaged gas cylinders, capable of exhibiting forceful and uncontrolled movements like rockets or spinning projectiles. This unsafe scenario holds the potential to cause severe injuries and extensive damage, often manifesting when an uncapped or inadequately secured cylinder is knocked over, leading to the breakage of the cylinder valve.

The handling of refrigerated liquefied gases, commonly known as cryogenic gases, necessitates particular attention due to their exceptionally low temperatures. Exposure to these frigid substances can result in cryogenic burns or frostbite injuries, underscoring the importance of adhering to stringent safety protocols when dealing with such materials in the workplace.

Always consult the Safety Data Sheet (SDS) and product CLP label to thoroughly understand the risks associated with the specific product you are working with. When in doubt, seek clarification and ask questions to ensure safety.

Protective measures for gases under pressure

When working with gases under pressure, safety measures are paramount. It is advisable to equip yourself with suitable personal protective equipment (PPE), which may include cold or heat-insulating gloves, specialised clothing, as well as eye and face protection. These precautions are essential to safeguard against potential mishaps.

To safely handle products marked with the gas cylinder pictogram, follow these guidelines:

  1. Review safety information: Always consult the Safety Data Sheet (SDS) and product label to understand hazards and precautions. If uncertain, seek clarification.
  2. Consider substitutes: If feasible, replace hazardous products with less risky alternatives.
  3. Prevent gas release: Use products in well-ventilated areas and minimise quantities for tasks.
  4. Protect your eyes: Wear chemical safety goggles or face shields when working with pressurised gases.
  5. Proper PPE training: Employers should train workers on selecting, wearing, and maintaining personal protective equipment (PPE) as indicated in the SDS.
  6. Gas cylinder handling: Inspect cylinders and valves for damage. Use suitable regulators and secure cylinders upright. Keep valves closed when not in use. Avoid adding lubricants or tape to valves. Prevent contamination.
  7. Safe transportation: Use proper equipment to move cylinders and avoid dropping or banging them.
  8. Refrigerated liquefied gases: Wear cold insulating gloves, a face shield, or eye protection. Refrain from wearing accessories that can freeze to skin if exposed to cold gas. Ensure equipment can withstand low temperatures and cool receiving containers beforehand.
  9. Awareness: Maintenance personnel should be informed about potential hazards and required precautions before commencing work.

Safe storage for gases under pressure

For safe storage of products bearing the gas cylinder pictogram:

  1. Sunlight protection: Shield from direct sunlight and ensure well-ventilated storage.
  2. Incompatible materials: Keep away from incompatible substances and potential ignition sources.
  3. SDS guidance: Adhere to SDS instructions, including storage quantities, temperature requirements, and separation distances.
  4. Leak detection: Consider using leak detection and alarm systems for added safety.
  5. Warning signs: Post warning signs and keep cylinders clear of exits.
  6. Secure upright position: Store cylinders upright, securely fastened with valve protection caps intact.
  7. Limit quantity: If possible, avoid storing excessive quantities.
  8. Follow supplier recommendations: Respect supplier-recommended storage durations.
  9. Label and inventory: Label containers with received, opened, and disposal dates, and use a first-in, first-out inventory system.
  10. Dispose promptly: Properly dispose of “empty” or unlabelled cylinders in a timely manner.
  11. Regulatory compliance: Comply with relevant by-laws, Fire Codes, and workplace safety regulations in your jurisdiction.

Conclusion

We have explored the significance of the gas cylinder pictogram in ensuring safety measures when dealing with products in various industries. Whether you are involved in the flavour, fragrance, and essential oil industry or any other sector that uses products with compressed gas, understanding and adhering to the recommended safety precautions is crucial.

By acknowledging the potential risks associated with gas cylinders, such as leakages and fire hazards, and implementing appropriate safety measures, we create a safer working environment for employees and minimise the possibility of accidents. Storing, transporting, and handling these products in accordance with the gas cylinder pictogram guidelines is essential to protect not only our employees but also our customers and the environment.